The August 2014 couple last appeared in photos together in November 2015.
Brad, 52, and Angelina, 41, were present at the film’s premiere, By The Sea, which the actress directed.
The couple joked and laughed together on the Los Angeles red carpet during their final public appearance.
As they posed for photos, Angelina put her hand on Brad’s chest and the two looked happy together.
The Oscar-winning actress and humanitarian put her arms around her husband while laughing in a strapless gown.
Brad stood by his wife during the film’s premiere, holding her hand during the gala opening night.
The movie, which Angelina co-directed and starred in with her husband, is about a couple who are dissatisfied with their marriage.
Regarding the movie, Angelina stated that it was challenging to work on at certain points.
It served as our means of self-examination. We were confident that we would emerge from this stronger and happier than when we started. And we carried it out.
“We’ve always enjoyed pushing ourselves, even though it was maybe a little more dangerous for us as a couple,” she continued.But I don’t think we want to experience that once more.
Angelina’s at torney confirmed the shocking news of their divorce, stating that papers were filed on Monday, citing irreconcilable differences.
The date of separation is listed as September 15, 2016, even though they haven’t been pictured together since the premiere.
The Tomb Raider actress is reportedly requesting physical custody of their six kids, according to TMZ.
Instead of joint custody, she allegedly requested that the judge grant the Fight Club actor visitation rights.
Together, the couple has three adopted children and three biological children.